Hierarchical MFI Zeolite Catalysts: How to Determine Their Textural Properties?-A Comparative Study
نویسندگان
چکیده
It is important to elucidate the role of surface areas and pore volumes hierarchical zeolites understand their behavior as catalysts. Micro-and mesopore MFI (Mobil Five zeolites) were assessed following several methods: (i) N2 adsorption at 77 K using classical corrected t-plot analyses methods, (ii) pre-adsorption n-nonane was followed by study K, (iii) non-local-density functional theory (NLDFT) analysis either method or Ar 87 K. In order assess viability each method, a set MFI-type prepared different approaches: alkaline treatment (desilication), synthesis in clear solution (nanocrystals), presence bifunctional organic surfactant (nanosheets), micelle-templating assisted treatment. NLDFT methods could not be used accurately determine micro-and areas, larger compared those obtained BET equation obtained. This overestimation even more pronounced with Results from performed under conditions for mechanical mixtures MCM-41 revealed underestimation micropore areas. Corrections provided analysis. The results good agreement during calculation zeolites. Micropore calculated characterized large zeolite domains. Ar, can However, it cannot efficiently calculate both
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ژورنال
عنوان ژورنال: Catalysis Research
سال: 2022
ISSN: ['2771-490X', '2771-490X']
DOI: https://doi.org/10.21926/cr.2202009